Abstract

The present review is devoted to the chemistry of trimethylacetate NiII complexes with various nitrogen-containing ligands. Pathways of formation of complexes containing the Ni2(μ-OH2)(μ-OOCCMe3)2 and Ni2(μ-OOCCMe3)4 fragments are discussed. Pathways of degradation of the nine-nuclear complex Ni9(HOOCCMe3)4(μ4-OH)3(μ3-OH)3)3(μ4-OOCCMe3)12 under the action of primary amines (aniline or propargylamine) as well as the process of dehydration ofN-phenyl-o-phenylenediamine up to the bischelate mononuclear complex [1,2-(NH)(NPh)C6H4]2Ni are demonstrated.

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