Abstract
Cationic single-bridged trinuclear cyano complexes are obtained by treating trihydrocarbyltin perchlorate (SnR 3O 2ClO 2) (R alkyl or aryl) with neutral transition metal monocyanides, whereas treatment with the corresponding neutral or anionic transition metal polycyanides gives neutral single-bridged polymeric cyano compounds. In every case the tin atoms are pentacoordinated with the three R groups in the equatorial and two CN groups (or, respectively one CN and one OClO 3 group) in the axial position of a trigonal bipyramid.
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