Triggering Dual Two-electron Pathway for H2 O2 Generation by Multiple [Bi-O]n Interlayers in Ultrathin Bi12 O17 Cl2 towards Efficient Piezo-self-Fenton Catalysis.

Abstract

Piezo-self-Fenton system (PESF) has been emerging as a promising water treatment technology but suffering from unsatisfied H2 O2 production efficiency. Herein, we rationally design a Bi12 O17 Cl2 piezo-catalyst with multiple [Bi-O]n interlayers towards highly efficient H2 O2 production. The introduction of [Bi3 O4.25 ] layers initiates dual two-electron pathway for H2 O2 generation by altering the interlayer properties. It is found that the additional [Bi3 O4.25 ] layers not only enhance the polarization electric field but also serve as active sites for triggering dual pathways of two-electron O2 reduction and H2 O oxidation reaction for H2 O2 production. Therefore, the Bi12 O17 Cl2 exhibits an ultrahigh rate of H2 O2 generation (7.76 mM h-1 g-1 ) in pure water. Based on the adequate H2 O2 yield, a PESF was constructed for acetaminophen (ACE) degradation with an apparent rate constant of 0.023 min-1 . This work not only presents a potential strategy of tuning the activity of bismuth based piezo-catalysts but also provides a good example on the construction of highly efficient PESF for environmental remediation by using natural mechanical energy.