Trifunctional Trichloroacetic Acid Incorporated Mixed-Halide Perovskites for Spectrally Stable Blue Light-Emitting Diodes.

Abstract

Metal halide perovskites have won great recognition in light-emitting diodes (LEDs). Nevertheless, the development of blue perovskite LEDs is facing a bottleneck in improving the device performance. Although mixed chloride/bromide perovskites can achieve pure-blue emission straightforwardly, higher chloride content will induce the challenges of low photoluminescence quantum yield and poor spectra stability resulting from the chloride vacancy defects and resultant halide ion migration under an electric field. In this work, we introduce a reliable trifunctional additive trichloroacetic acid into mixed-halide perovskites, which can provide additional chloride to fill halide vacancies, passivate the uncoordinated Pb2+ ion defects, and promote the crystallization effectively. Owning to the utilization of trichloroacetic acid, the ultimate pure-blue perovskite LED obtains stable electroluminescent spectra at 477 nm under various bias and demonstrates a 5-fold external quantum efficiency improvement (up to 6.6%).