Abstract
AbstractIn this study, a radical‐triggered cyclization of o‐alkenyl aromatic isocyanides prepared from accessible starting materials is developed. The reaction provides a general and efficient method for the synthesis of 4‐CN‐2‐CF3/CF2H‐containing quinolines under copper or visible‐light photoredox catalysis in a one‐pot synthetic procedure. This protocol demonstrates good to high yields, broad substrate scope, and good functional group tolerance.magnified image
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