Abstract
1. The thermal and photoinduced reactions of Cp2MMMe2 (M=Ti, Zr) with Et3EH (E=Ge, Sn) produce 1 mole of Et6E2, 2 moles of methane, and 1 mole of Cp2M. Compounds with the general formula Cp2M(EEt3)2 could not be obtained. 2. The exchange reaction of Cp2MCl2 (M=Ti, Zr) with Et3ELi (E=Ge, Sn) in THF or toluene at −40°C results in the formation of compounds with the general formula Cp2M(EEt3)2, which decompose at 20°C, yielding 1 mole of Et6E2 and an adduct of the biscyclopentadienyl derivative of the metal with THF.
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