Abstract
The X-ray crystal structure of tris[N-(2-hydroxyethyl)-2,2'-iminodiethanolato]tris(2,2',2''-nitrilotriethanolato)tetrairon(II)triiron(III) bis(perchlorate), [Fe7(C6H12NO3)3(C6H13NO3)3](ClO4)2 or [Fe7(tea)3(tea-H)3](ClO4)2 (tea-H3 is triethanolamine), is known from the literature [Liu et al. (2008). Z. Anorg. Allg. Chem. 634, 778-783] as a heptanuclear coordination cluster. The space group was given as I213 and is reinvestigated in the present study. We find a new space-group symmetry of Pa-3 and could detect O-H hydrogens, which were missing in the original publication. Consequences on the Fe oxidation states are investigated with the bond-valence method, resulting in a mixed-valence core of four FeII and three FeIII centres. Symmetry relationships between the two space groups and the average supergroup Ia-3 are discussed in detail.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
