Abstract
A new type of α-diketone palladium(II) complex containing a tertiary phosphine, namely the title compound, [Pd(C7H5O2)2(C18H33P)], crystallizes with a square-planar geometry about the palladium(II) metal centre. One tropolonate ligand is bonded in a bidentate chelating mode, while the second one is bonded through a single O atom to the palladium(II) metal centre. The Pd—O distances range from 1.9907 (13) to 2.0702 (12) Å, and the O—Pd—O bite angle for the bidentate tropolonate ligand is 80.30 (5)°.
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