Tricyclohexyl[2-(2,3-dimethylanilino)benzoato-κO]tin(IV)

Muhammad Danish,M Nawaz Tahir,Amin Badshah,Nazir Ahmad,Saqib Ali

doi:10.1107/s1600536809048314

Muhammad Danish, M Nawaz Tahir + Show 3 more

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https://doi.org/10.1107/s1600536809048314

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Abstract

In the title compound, [Sn(C6H11)3(C15H14NO2)], the SnIV atom adopts a distorted tetrahedral SnOC3 arrangement. The dihedral angle between the benzene rings in the mefanamic acid molecule is 82.16 (17)° and intramolecular N—H⋯O and C—H⋯O hydrogen bonds help to establish the conformation. Two of the cyclohexyl rings are disordered over two sets of sites with equal occupancies.

Highlights

In the title compound, [Sn(C6H11)3(C15H14NO2)], the Sn atom adopts a distorted tetrahedral SnOC3 arrangement
Two of the cyclohexyl rings are disordered over two sets of sites with equal occupancies
We reported the crystal structures of (II) {2-[(2,3-Dimethylphenyl)amino]benzoato-O:O′}-trimethyltin(IV) (Tahir et al, 1997a), (III) (Ketoprofenato)trimethyltin(IV) (Tahir et al, 1997b) and recently (IV) Bis(μ3-Oxo)-bis(μ2-2- ((3-thiophene)acetato-O,O′)-octa-methyl(2-((3-thiophene)acetato-O)- tetra-tin(IV) (Danish et al, 2009)

Summary

Saqib Alic and Amin Badshahc

H atoms treated by a mixture of independent and constrained refinement max = 1.37 e Å 3. Min = 0.49 e Å 3 a Selected bond lengths (Å). Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.009 Å; disorder in main residue; R factor = 0.056; wR factor = 0.166; data-to-parameter ratio = 25.0. In the title compound, [Sn(C6H11)3(C15H14NO2)], the Sn atom adopts a distorted tetrahedral SnOC3 arrangement. The dihedral angle between the benzene rings in the mefanamic acid molecule is 82.16 (17) and intramolecular N—H O and. C—H O hydrogen bonds help to establish the conformation. Two of the cyclohexyl rings are disordered over two sets of sites with equal occupancies

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