Abstract
Oxorhenium(V) complexes of β-diketonate systems have been synthesized and isolated in pure form. The red complexes n-Bu4N[ReO(R1COCHCOR2)Cl3] (acac, R1=R2=CH3; bzac, R1=CH3 and R2=C6H5; bzbz, R1=R2=C6H5) have been characterized by elemental analyses, spectroscopic and other physico-chemical tools. One complex, n-Bu4N[ReO(bzbz)Cl3] (1c) has been subjected to single-crystal X-ray analysis. In the structure of the anion, the metal has a six-coordinate octahedral environment in which the bidentate β-diketone ligand is cis and trans to the terminal oxygen.
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