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Abstract
The structure of the title compound, [Mo(C5H5)Cl(CO)3], reveals a pseudo-square-pyramidal piano-stool coordination around the MoII ion, which is surrounded by a cyclopentadienyl ring, three carbonyl groups and a chloride ligand.
Highlights
The structure of the title compound, [Mo(C5H5)Cl(CO)3], reveals a pseudo-square-pyramidal piano-stool coordination around the MoII ion, which is surrounded by a cyclopentadienyl ring, three carbonyl groups and a chloride ligand
We acknowlege the finacial support from the NRF (THUTHUKA), the University of the Western Cape and Sanate Research
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: KP2389)
Summary
The structure of the title compound, [Mo(C5H5)Cl(CO)3], reveals a pseudo-square-pyramidal piano-stool coordination around the MoII ion, which is surrounded by a cyclopentadienyl ring, three carbonyl groups and a chloride ligand. Related literature For related structures, see: Chaiwasie & Fenn (1968); Churchill & Bueno (1981); Albright et al (1978); Mays & Robb (1968). For applications of this class of compounds, see: Arzoumanian (1998); Freund et al (2006); Karunadasa et al (2010). See: Amor et al (2000); Atwood & Barbour (2003)
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