Tribological Performance Study of HVOF-Sprayed Microstructured and Nanostructured WC-17wt.%Co Coatings

Abstract

Abrasive and erosive wear of components and machinery is an ongoing challenge in the oil sands industry in northern Alberta, Canada. To improve the wear resistance by increasing surface hardness of steels, heat treatments and deposition of hard layers of metal alloys (such as stellite) by fusion welding techniques are traditionally used. However, these deposition techniques are not applicable to all shapes and add considerable weight to the final component. Thermal spraying techniques such as the use of high velocity oxy-fuel (HVOF) composite coatings based on WC-Co cermet system offer better wear resistance and greater flexibility in applications. This study presents work on two feedstock powders, namely nanocrystalline and microcrystalline WC-Co cermets, with identical matrix phase content: WC-17wt.%Co. The novelty of the research is that an engineered duplex Co coated WC-17wt.%Co cermet particle designed to withstand coating spalling under elevated loads as well as to limit abrasive debridement during wear is introduced for the first time to produce a more homogeneously-dispersed coating microstructure. The engineered particle has 6wt.% of the ductile phase material mixed into the core to insure that the reinforcement WC phase is discontinuous to limit the debridement during wear, while remainder (11wt.%) of the Co is applied as a coating on the particle to improve the ductility. The mechanical properties of the overall particle are further improved by controlling the size of the reinforcing phase (WC) in the matrix (Co). This resulted in a WC-17wt.%Co particle containing a characteristic WC grain in the order of 350 nm in the core with the Co outer coating of 1–2 μm thick, making the powder particle as nanocrystalline. HVOF deposited coatings of the nanocrystalline and microcrystalline powders were examined for microhardness, fracture toughness, sliding abrasion (ASTM G133-05) and dry-sand rubber wheel abrasion (ASTM G65-04) wear performance. The wear rate under various loads and sliding distances was studied. In both the coatings, it was found that the wear rate increased with increasing applied loads, while it decreased with increasing sliding distances. 3D surface analysis of the wear tracks using atomic force microscopy (AFM) revealed two distinctive mechanisms associated with the two coatings after abrasive wear. The improved wear resistance was attributed to the higher hardness value of the nanostructured WC-17wt.%Co coating. It was also found that the nanostructured WC-17wt.%Co coating has about twice the toughness of the conventional microstructured coating counterpart. The extent of the WC decarburization and the dissolution of Co in the coatings were also studied.