Abstract
The cycloaddition reaction of acetone t-butylhydrazone (6) with cyanic acid yielded the 1,2,4-triazolidin-3-one 1c, subsequent oxidative ring-opening afforded the t-butylazoalkyl isocyanate 3c. Derivatization of the isocyanate function of 3c furnished the carbamic acid derivatives 7-10. Reactions involving both geminal functional groups of 3c led to the heterocycles 11, 12, and the title compound 4c; some properties and reactions of the triazolium salt 4c are described
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