Abstract
The application of mono-triazole-annulated phthalocyanine and benzoporphyrazine complexes for the functional unsymmetrical modification of the macrocycle's periphery is discussed. The peculiarities of the synthesis of some metal complexes with aryloxy-substituted mono-triazole-annulated Pc are described. Alkylation by ω-alkenylbromide of the triazole ring in accordingly prepared novel mono-triazole-annulated phthalocyaninato nickel, as well as in mono-benzotriazole-annulated porphyrazinato zinc, is studied. The terminal double bond in the formed derivatives could be successfully converted into acetylsulfanyl function only in the case of phthalocyaninato nickel complex due to the instability of porphyrazinato zinc under the reaction conditions.
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