Abstract
Increasing levels of CO2 in the atmosphere have led to serious problems. In view of this, we synthesized nanoarchitectonics porous organic polymers (NPOPs) by a catalyst-free coupling reaction between cyanuric chloride and 4,4-diaminoazobenzene or bisphenol-A in a polymer framework involving a nucleophilic substitution reaction for CO2 capture. Fourier transform infrared spectroscopy, solid-state 13C NMR spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy results confirmed polymerization, while Thermogravimetric analysis showed that the NPOPs were thermally stable. The surface morphology was observed using scanning electron microscopy. BET surface area analysis indicated the presence of micropores. The CO2 uptake of NPOP-1 and NPOP-2 was observed. The NPOPs may have potential for application in carbon capture and storage technology.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.