Abstract
Aryl, heterocyclic, benzyl, and vinylic halides undergo facile reactions with carbon monoxide or olefins forming new carbon-carbon bonds under the influence of triarylphosphine-palladium catalysts. The carbon monoxide reactions produce esters in the presence of alcohols, amides in the presence of amines, and aldehydes in the presence of hydrogen. Reactions with olefins produce new olefins in which a vinylic hydrogen is replaced by the organic group from the halide. Some olefins and vinylic halides require the presence of secondary amines to react, in which instance tertiary allylic amines are formed catalytically. Conjugated dienes may be used in place of simple olefins to form products with additional unsaturation. Numerous applications for these reactions in organic synthesis appear likely.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
