Triarylamine-based polyamide containing adamantane group as Fe3+ probe and electrochromic smart devices

Abstract

A new triarylamine-based polyamide was synthesized from 1,4-cyclohexanedicarboxylic acid and diamine monomer containing adamantane group (PA-CA), which exhibits high fluorescence quantum up to 46.1% and excellent electrochromic behaviors. The photoluminescence of PA-CA was quenched by coordination and internal filtration effect to realize Fe3+ response. Neutral colorless PA-CA film was converted to the oxidized blue in the electrochemical oxidation process and the maximum transmittance reached 80%, and the transmittance still exceeded 55% after 10,000 s. A Sandwich structure electrochromic device with PA-CA as the active layer was constructed with a simple strategy and different contents were displayed through patterned customization. Electrofluorochromic performance was regulated and decoding information was customized by applying voltage changes of the light and dark for PA-CA film. The applications of multifunctional integrated PA-CA responding to stimulus have broad prospects in the field of Fe3+ fluorescence sensors, photodetectors and multicolor electrochromic display devices.