Abstract

Definitive evidence for the formation of a long-lived trivalent tin cation was obtained by using a well-defined reaction, i.e. the abstraction of hydride from tributyltin by trityl tetrakis[3,5-bis(trifluoromethyl)phenyl]borate in dichloromethane- d 2. The 119Sn resonance at around 360 ppm is indicative of no significant interaction between the tin cation and the counteranion.

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