Abstract
The title hydrate, Me3PO·2H2O, crystallizes in the ortho-rhom-bic space group Pbca with eight formula units per unit cell. The extended structure displays O-H⋯O hydrogen bonding, with Me3PO mol-ecules as acceptors and water mol-ecules acting as donors and acceptors of hydrogen bonds, forming hydrogen-bonded layers, which propagate in the ac plane.
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