Abstract

New trinuclear cluster compounds [Pt3(CO)3L4](L = PPh3, PPh2Me, and PPh2Et) and [Pt3(CO)3L3](L = PPh2PhCH2) are obtained by decomposition of the complexes [Pt(CO)2L2]; however their preparation is generally more convenient without the isolation of [Pt(CO)2L2], from an alkali tetrachloroplatinate, a phosphine, and carbon monoxide.

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