Abstract

In the title compound, [SmTi2Cl7O(C4H8O)6], the metal ions are linked by a central mu3-oxo ion and by three mu2-chloro ions, giving a planar moiety containing a binary crystallographic axis. The coordination spheres are completed by terminal chloro ligands and tetrahydrofuran molecules, with resulting pentagonal bipyramidal and octahedral environments for the Sm and Ti atoms, respectively.

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