Abstract

Diffuse interstellar bands (DIBs) are absorption features commonly observed in optical/near-infrared spectra of stars and thought to be associated with polyatomic molecules that comprise a significant reservoir of organic material in the universe. However, the central wavelengths of almost all DIBs do not correspond with electronic transitions of known atomic or molecular species and the specific physical nature of their carriers remains inconclusive despite decades of observational, theoretical, and experimental research. It is well established that DIB carriers are located in the interstellar medium, but the recent discovery of time-varying DIBs in the spectra of the extragalactic supernova SN2012ap suggests that some may be created in massive star environments. Here we report evidence of short time-scale (10-60 d) changes in DIB absorption line substructure toward 3 of 17 massive stars observed as part of a pathfinder survey of variable DIBs conducted with the 1.5-m Tillinghast telescope and Tillinghast Reflector Echelle Spectrograph (TRES) at Fred L. Whipple Observatory. The detections are made in high-resolution optical spectra (R = 44000) having signal-to-noise ratios of 5-15 around the 5797 and 6614 angstrom features, and are considered significant but requiring further investigation. We find that these changes are potentially consistent with interactions between stellar winds and DIB carriers in close proximity. Our findings motivate a larger survey to further characterize these variations and may establish a powerful new method for probing the poorly understood physical characteristics of DIB carriers.

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