Trends in oolite dolomitization across the Neoproterozoic–Cambrian boundary: A case study from Death Valley, California

Abstract

Changes in dolomite fabric within the Neoproterozoic–Cambrian stratigraphic succession in Death Valley, California preserve evidence for a first-order biogeochemical change in early diagenetic environments through the Neoproterozoic–Cambrian transition. Oolite forms the primary focus of the study so that the general paleoenvironmental setting and presumed susceptibility to early diagenesis and fluid flow can be kept relatively constant across geologic time. Two key generalizations can be made: (1) late Neoproterozoic dolomitization in Death Valley occurred very early in the paragenetic sequence, was volumetrically significant, and preserved fine detail of the original aragonite or calcite precursor; and (2) Early Cambrian dolomitization in Death Valley occurred late in the paragenetic sequence with burial, was commonly incomplete, and obliterated details of the calcite or aragonite precursor; early diagenetic dolomitization of any kind was absent. The dolomitization fabrics in Death Valley parallel the presumed pattern of seawater Mg/Ca with respect to mimetic dolomitization in the Paleozoic (low Mg/Ca, little/no mimetic dolomitization) and Cenozoic (higher Mg/Ca, more common mimetic dolomitization). However, the volume of Neoproterozoic mimetic dolomitization is immense compared to the Cenozoic examples. We speculate that a fundamental shift in the early diagenetic environment occurred in late Neoproterozoic time, perhaps in association with secular variation in the sulfate concentration of seawater and the advent and proliferation of penetrative bioturbation that destroyed sediment-capping microbial mats. An oscillatory trend in the fabric and volume of dolomite through the Phanerozoic has been suggested, but the termination of volumetrically significant mimetic dolomitization across the Neoproterozoic–Cambrian transition, a critical time in Earth history for many reasons, dwarfs the oscillatory trends noted in the Phanerozoic.