Treatability study using novel activated carbon prepared from rice husk: Column study, optimization using response surface methodology and mathematical modeling

Abstract

In this present study, activated carbon was synthesized from rice husk and was used for the removal of fluoride present in water. The adsorption of fluoride from aqueous solution by activated carbon (ACRH) was investigated in a laboratory-scale fixed-bed column. A two-level three factor (23) full factorial central composite design with the help of Design Expert Version 7.1.6 (Stat Ease, USA) was used for optimization of the fluoride removal process and evaluation of interaction effects of different operating parameters: initial fluoride concentration (20–50mgL−1), flow rate (5–10mLmin−1) and bed height (3–7cm) were studied. The higher correlation coefficient (R2) value of 0.9893 and low p value (<0.0001) indicating the fitness of the response surface quadratic model developed by the Design expert optimization process. Numerical optimization was used to identify the optimum conditions for achieving the targeted breakthrough time of 17.26h. The optimum conditions were found to be initial fluoride concentration of 50mgL−1, flow rate of 10mLmin−1and bed height of 3cm. A confirmatory experiment was conducted to evaluate the accuracy of the optimized procedure. The Thomas model showed excellent fit to the dynamic fluoride adsorption data obtained from the experimental results. Therefore, it can be concluded that the current investigation provided valuable insights for designing and establishing a continuous waste water treatment process.