Abstract
Methoxy formed on Al2O3 from13CO and H2 coadsorption on Ni/Al2O3 was trapped by C2H5OH adsorption and temperature-programmed reaction (TPR). The presence of excess C2H5OH significantly increases the rate of13CH3OH and (13CH3)2O formation. The13CH3OH forms by the reaction of C2H5OH with13CH3O on Al2O3. In the absence of C2H5OH,TPR following13CO and H2 coadsorption did not produce significant amounts of13CH3OHor(13CH3)2O.
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