Abstract

ABSTRACTIndium and cerium added cobalt-antimony based skutterudites with different filling fractions were synthesized using different annealing synthesis parameters. Phase homogeneity and microstructure of the resulting as-cast material were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The skutterudite material was further compacted using a current-assisted short-term sintering device. Temperature dependent measurements of the Seebeck coefficient, electrical and thermal conductivity were carried out on the compacted specimens in the temperature range of 350 K-700 K. Results indicate significant differences in the transport properties between the slowly cooled and quenched as‑cast materials and also with different filling fractions. Based on the measured transport properties the dimensionless figure of merit ZT was calculated for different filling fractions of indium and cerium. Among these compositions a ZTmax of 1.1 at 700 K was obtained.

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