Transport of Tb3+ in Dispersion Supported Liquid Membrane System with Carrier P507

Abstract

AbstractThe Tb3+ transport in dispersion supported liquid membrane (DSLM) consisting of polyvinylidene fluoride membrane (PVDF) as the liquid membrane support and dispersion solution including HCl solution as the stripping solution and 2‐ethyl hexyl phosphonic acid‐mono‐2‐ethyl hexyl ester (P507) dissolved in kerosene as the membrane solution, has been studied. The effects of pH value, initial concentration of Tb3+ and different ionic strength in the feed phase, volume ratio of membrane solution and stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on transport of Tb3+ has also been investigated, respectively. As a result, the optimum transport conditon of Tb3+ was that concentration of HCl solution was 4.0 mol/L, concentration of P507 was 0.10 mol/L, and volume ratio of membrane solution and stripping solution was 1.0 in the dispersion phase, and pH value was 5.2 in the feed phase. Ionic strength had no obvious effect on transport of Tb3+. Under the optimum condition studied, when initial concentration of Tb3+ was 1.0×10−4 mol/L, the transport rate of Tb3+ was up to 95.2% during the transport time of 95 min. The kinetic equation was developed in terms of the law of mass diffusion and the theory of interface chemistry. The results were in good agreement with the literature data.