Abstract

Experiments on the transport of beryllium in beryllium dichloride vapour at about 1 × 10–4 atmospheres have been made in the temperature range from 1250 to 1500 K. The transport can well be interpreted as resulting from the reaction Be(s)+ BeCl2(g)= 2BeCl(g)(1) and agrees with that extrapolated from previous transport experiments by Greenbaum, Arin, Wong and Farber between 1570 and 1725 K. A third law analysis of all the experiments leads to ΔH°f298, BeCl(g)= 1.7±0.7 kcal/mol.

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