Abstract

In a growing number of strongly disordered and dense systems, the dynamics of a particle pulled by an external force field exhibits super-diffusion. In the context of glass forming systems, super cooled glasses and contamination spreading in porous medium it was suggested to model this behavior with a biased continuous time random walk. Here we analyze the plume of particles far lagging behind the mean, with the single big jump principle. Revealing the mechanism of the anomaly, we show how a single trapping time, the largest one, is responsible for the rare fluctuations in the system. These non typical fluctuations still control the behavior of the mean square displacement, which is the most basic quantifier of the dynamics in many experimental setups. We show how the initial conditions, describing either stationary state or non-equilibrium case, persist for ever in the sense that the rare fluctuations are sensitive to the initial preparation. To describe the fluctuations of the largest trapping time, we modify Fr\'{e}chet's law from extreme value statistics, taking into consideration the fact that the large fluctuations are very different from those observed for independent and identically distributed random variables.

Highlights

  • Diffusion and transport in a vast number of weakly disordered systems follow Gaussian statistics

  • In the context of glass-forming systems, supercooled glasses, and contamination spreading in porous media, it was suggested that this behavior be modeled with a biased continuous-time random walk

  • These nontypical fluctuations still control the behavior of the mean square displacement, which is the most basic quantifier of the dynamics in many experimental setups

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Summary

INTRODUCTION

Diffusion and transport in a vast number of weakly disordered systems follow Gaussian statistics. In the presence of deep traps, the MSD exhibits superdiffusion This is not an indication for a fast process, instead it is due to the very slow particles far lagging behind the mean, which lead to very large fluctuations of displacements. Slow dynamics of a minority of particles leads to enhanced fluctuations and symmetry breaking with respect to x(t ) Such processes are widespread; in particular, many works focused on the surprising discovery of the superdiffusion in dense environments [3,4,5,6,7,8]. We present an analysis of the far tail of the spreading of the packet of particles, showing the deviations from the Lévy statistics describing the bulk statistics This is done for both nonstationary and equilibrium initial conditions.

Model and definition
Main results
Statistics of τmax
Rare fluctuations of τmax
Rare fluctuations of the position
EQUILIBRIUM CASE
Findings
DISCUSSION AND SUMMARY
Full Text
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