Transparent polycrystalline alumina obtained by SPS: Green bodies processing effect

Abstract

Starting from a commercial slurry of high purity α-Al2O3, freeze-dried powders, cast, filter-pressed or cold isostatically pressed samples were produced. Resulting powders or green bodies showing different particles packing were densified by spark plasma sintering (SPS) to obtain transparent polycrystalline α-Al2O3. Microstructure and real in-line transmittance (RIT) after SPS were dependent on the particles packing quality. Avoiding large agglomerates, narrowing the pore size distribution, reducing the most-frequent pore size (Dmode) and avoiding macroscopic heterogeneities within the green bodies enabled high RIT values to be achieved in the visible and near-infrared spectrum. However, a limit was achieved in the preparation of green bodies for which reducing the Dmode had no more influence on the optical behaviour of samples sintered by SPS. Finally, pure α-Al2O3 samples presenting a high RIT640 nm value of 53% were produced from all the green bodies obtained by the following techniques: filter-pressing, slip casting and cold isostatic pressing.