Transmission Line Circuit and Equation for an Electrolyte-Filled Pore of Finite Length.

Abstract

I discuss the strong link between the transmission line (TL) equation and the TL circuit model for the charging of an electrolyte-filled pore of finite length. In particular, I show how Robin and Neumann boundary conditions to the TL equation, proposed by others on physical grounds, also emerge in the TL circuit subject to a stepwise potential. The pore relaxes with a timescale τ, an expression for which consistently follows from the TL circuit, TL equation, and from the pore's known impedance. An approximation to τ explains the numerically determined relaxation time of the stack-electrode model of Lian etal. [Phys. Rev. Lett. 124, 076001 (2020)PRLTAO0031-900710.1103/PhysRevLett.124.076001].