Abstract

Translational energy spectroscopy (TES) of NO + ions formed by Ar + charge exchange has been studied. The two features observed in the spectrum are assigned to transitions from the υ″ = 0 and possibly υ″ = 1 and 2 levels of the a 3Σ + state to the low vibrational levels of the w 3Δ and b′ 3Σ − states. Comparison with previous TES spectra of NO + formed by electron impact is reported and demonstrates the high selectivity of the charge transfer reaction in populating the first excited state of NO +.

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