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https://doi.org/10.1021/acs.orglett.7b03192
Copy DOIJournal: Organic letters | Publication Date: Nov 7, 2017 |
Citations: 17 |
The transition-metal-free diastereoselective C(sp2)-C(sp3) cross-coupling between unprotected diols and boronic acids or potassium organotrifluoroborates is reported. Depending on the reaction conditions, the syn or the anti reaction products are obtained in a stereocomplementary fashion. This type of coupling is developed with alkenyl-, heteroaryl- and arylboron compounds as carbon nucleophiles.
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