Abstract
Oxidative Heck reactions provide a facile and efficient routeto carbon-carbon bond formations. This review is dividedinto two main sections, the first consisting of oxidative Heck reactions oforganometallic compounds such as organoboranes, organosilanols andarylstannanes, and the second covering oxidative Heck reactionsvia C-H activation, a topic which has become an attractive themein organic synthesis. 1 Introduction 2 Oxidative Heck Reactions of Organometallic Compounds 2.1 With Palladium(II) Catalysts 2.1.1 Ligand-Free Reactions 2.1.1.1 Anaerobic 2.1.1.2 Aerobic 2.1.2 Ligand-Based Reactions 2.1.2.1 Aerobic 2.1.2.2 Anaerobic 2.1.3 Asymmetric Reactions 2.1.3.1 Aerobic 2.1.3.2 Anaerobic 2.1.4 With Polymer-Supported Palladium(II) Catalysts 2.2 With Other Transition-Metal Catalysts 2.3 With Other Organometallic Compounds 3 Oxidative Heck Reactions of C-H Compounds 3.1 Catalytic Reactions 3.1.1 Intermolecular Reactions 3.1.1.1 Anaerobic 3.1.1.2 Aerobic 3.1.2 Intramolecular Reactions 3.1.2.1 Anaerobic 3.1.2.2 Aerobic 4 Conclusions and Outlook
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