Abstract
AbstractThe transition temperature, defined as the temperature where the log modulus temperature curve has an inflection point, is a linear function of the volume fraction of compatible plasticizer added to a high polymeric resin such as polyvinyl chloride. The transition temperature of plasticized compositions can be predicted from the transition temperatures of the pure polymer and plasticizer. The transition temperature of homogeneous copolymers can be predicted from the transition temperature of the individual polymerized monomers making up the copolymer. Data are presented on three copolymer systems containing vinyl chloride and on various plasticized materials.
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