Abstract
The synthesis of seven bi- and tricyclic chorismate analogues 9 - 15 and their biological evaluation as mutase inhibitors is described. A tandem Cope rearrangement/Diels-Alder cycloaddition strategy was employed to prepare tricyclo[3.3.1.0 2,7]non-3-enes functionalized with carboxylic and/or phosphonic acid groups.
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