Abstract
The photochemical reaction of Cp′Mn(CO)3 with HMe2Si-1,2-C6H4-SiMe2H and of Cp′Mn(CO)2PMe3 with HMe2Si-X-SiMe2H (X=1,2-C6H4, C2H4, O) results in the formation of the oxidative addition products Cp′(CO)(L)Mn(H)SiMe2-X-SiMe2H. Except for the combination X= 1,2-C6H4 and L=PMe3, the binuclear complexes [Cp′(CO)(L)Mn(H)SiMe2]2 X are additionally formed.
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