Abstract
Reaction of Ph2PCH2CH2SiPh3-nMen (n = 0, 1) with (Ph3P)2Pt(π-C2H4) at elevated temperatures results in the formation of by oxidative addition of the Si−Cphenyl group. Oxidative addition of Si−Me groups is not observed. Therefore, no chelate complex is obtained with Ph2PCH2CH2SiMe3. The complex is formed when a mixture of PEt3 and Ph2PCH2CH2SiPh2Me is reacted with (Ph3P)2Pt(π-C2H4).
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