Abstract
The transition metal salts of heteropoly acids have been applied as palladium re-oxidants in heterogeneous solid Wacker catalysts for the oxidation of butene-1 to MEK. Silica, γ-alumina and titania were used as supports for the Pd/MeHPMoVx system. The influence of cations bonded to heteropoly anions and also the effect of the catalysts acidity on the butene-1 to MEK oxidation have been elucidated.
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