Abstract

The emergence of hydridotris(pyrazolyl)borate (Tp) and related ligands has had a substantial influence in the field of organometallic chemistry with regards to C–H activation. The electronic and structural properties of Tp and related ligands, such as poly(pyrazolyl)alkane ligands, play an important role in the ability of several transition metal complexes to mediate C–H activation and functionalization. Herein, several studies of stoichiometric and catalytic C–H activation by platinum group metals are reviewed.

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