Abstract
The annulation reactions between gem‐diamino enaminones (ketene aminals) and tosyl azide providing N‐heterocycle fused and 5‐amino side chain functionalized 1,2,3‐triazoles have been developed. The synthesis of these N‐side chain functionalized 1,2,3‐triazoles has been executed with high efficiency and broad synthetic scope under transition metal‐free conditions with the assistance of NaHCO3 only.
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