Abstract
The reactions of arenediazomolybdenum(II) complexes such as [(η-C 5H 5)Mo(N 2C 6H 4CH 3- p)I 2] 2, (η-C 5H 5)Mo(CO species with neutral and anionic monodentate or chelating ligands have been investigated. The new arenediazo complexes isolated from these reactions include neutral species such as (η-C 5H 5)Mo(PPh 3)(N 2C 6H 4CH 3- p)I 2 and (η-C 5H 5)Mo(N 2C 6H 4CH 3- p) cations of the type [η-C 5H 5)Mo(bipy)(N 2C 6H 4CH 3- p)I] + and the anion [(η-C 5H 5)Mo(N 2C 6H 4CH 3- p)I 3] −. The structures of the new complexes are discussed.
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