Abstract
Several square-pyramidal iron(IV) complexes with the quadridentate ligand pentane-2,4-dione bis(S-methylisothiosemicarbazone) (H 3L) of the type [Fe(L)X], where X = Cl, Br, NCO or NCS, were synthesized and their physicochemical characteristics, together with those of previously reported [Fe(L)I] and [Fe(L)] 2O, are described. The complexes were characterized by elemental analysis, molar conductivity and magnetic measurements, IR and electronic spectra. In addition, cyclic voltammetry is used to study the redox behaviour of the complexes in their DMF solutions and especially of the dimermonomer equilibria influenced by the acidity of the solution.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
