Abstract
The far-i.r. spectra (450–80 cm.–1) of 32 complexes formed by cobalt(II), nickel(II), and copper(II) halides with 1,2-dipyridylethylene isomers or 1,2-di-(4-pyridyl)ethane are described, and assignments discussed, particularly of ν(MX) modes. The structures previously suggested on the basis of magnetic and electronic spectral properties of the compounds are generally confirmed, and in some cases more definite evidence regarding the metal co-ordination environment is obtained. The origin of the ‘second X-sensitive band’ in octahedral copper(II) complexes is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
