Abstract
AbstractSince the pioneering work on Cr(III)‐catalyzed enantioselective [4+2]/allylboration reported by Hall and co‐workers, a variety of catalytic methodologies for the asymmetric allylic borylation reactions have been developed to provide chiral allylboronates bearing a wide range of functional groups. This review article describes recent advances in transition‐metal catalyzed preparation of chiral allylboronates, especially on those in the past three years, and with the emphasis on the aspect of asymmetric catalysis. According to the mechanism of achieving the chemo‐, regio‐, stereo‐ and enantioselectivities, the discussion is divided in two parts: substrate‐controlled and catalyst‐controlled synthesis.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
