Abstract
Carbon dioxide is not only an essential component of ‘greenhouse gases’, but also an abundant, renewable C1 feedstock in organic synthesis. The catalytic incorporation of carbon dioxide into value-added chemicals to produce carboxylic acids has received enormous attention. This review summarizes recent developments in the transition-metal-catalyzed carboxylation of organic halides and their surrogates, such as aryl, vinyl, and alkyl halides and pseudohalides.1 Introduction2 Carboxylation of Aryl Halides and Pseudohalides3 Carboxylation of Vinyl Halides and Pseudohalides4 Carboxylation of Benzyl Halides and Pseudohalides5 Carboxylation of Allyl Halides and Pseudohalides6 Carboxylation of Propargyl Halides and Pseudohalides7 Carboxylation of Alkyl Halides and Pseudohalides8 Direct Carboxylation of C–H Bonds9 Conclusions and Perspectives
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