Abstract
The absorption/emission spectra of excited states (singlets and triplets) and ions generated by pulse radiolysis method in the pyrene–Nafion system were investigated. Scavenging of positive charges by pyrene was only observed. Pyrene fluorescence (monomer and excimer) was found to be produced mainly as a result of Čerenkov photoexcitation. In addition, pyrene triplets can be generated by ionic recombination in μs times. The influence of matrix properties on pyrene ions yield was discussed.
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