Transient exchange fluctuation theorems for heat using a Hamiltonian framework: Classical and quantum regimes.

Abstract

We investigate the statistics of heat exchange between a finite system coupled to reservoir(s). We have obtained analytical results for heat fluctuation theorems in the transient regime considering the Hamiltonian dynamics of the composite system consisting of the system of interest and the heat bath(s). The system of interest is driven by an external protocol. We first derive it in the context of a single heat bath. The result is in exact agreement with known result. We then generalize the treatment to two heat baths. We further extend the study to quantum systems and show that relations similar to the classical case hold in the quantum regime. For our study we invoke von Neumann two-point projective measurement in quantum mechanics in the transient regime. The study of quantum systems follows the same lines of argument as that of the classical system, and as a result the treatment used in the latter complements that used in the former. Our result is a generalization of Jarzynski-Wòjcik heat fluctuation theorem.