Transient analysis of the cooling process of molten salt thermal storage tanks due to standby heat loss

Abstract

Molten salts consisting of 60% sodium nitrate and 40% potassium nitrate have been used successfully as a thermal energy collection and storage fluid in different solar thermal plants. However, the relatively high melting point of this mixture (221°C) represents an important risk of local solidification in the operation of the solar power plants during standby periods. In this work, a computational fluid dynamics (CFD) model is developed to analyze the cooling process of representative state-of-the-art molten salt thermal storage tanks during these standby periods. A comprehensive set of operating conditions is analyzed, covering both hot and cold storage tanks, charging levels, and heat losses. Results show that the onset of local crystallization is highly influenced by the tank charging level. While the risk is relatively high in the case of the minimum charging level, in the case of maximum charging level the risk is minimal as it would require a very long standby period. To summarize the results, this work presents a safe charging level calculation, as a function of the operation temperature and the expected standby duration, which could be used as part of an appropriate operational strategy to avoid the risk of freezing for long standby periods. The model assumptions, the different configurations studied and their results are presented and discussed in detail.