Abstract
The interaction of AuCl 4 - with thiourea (tu) at various Сtu/СAu ratios and transformations of the bis(thiourea)gold(I) complex in an alkaline aqueous solution have been studied. Both processes lead to a set of products. It has been demonstrated that formamidine disulfide is not the major product of thiourea oxidation. The precipitate forming upon the treatment of AuCl 4 - with an alkali contains Au2S and an organic part, which is likely a polymeric compound [Au(tu-H)]n.
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